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Due to insufficient sorting and recycling, macroscopic contaminations remain in post-consumer polyolefin recyclates. It is known that these contaminations affect the mechanical properties of the recyclates, as they constitute defects and thus crack initiators. However, the influences of different types and amounts of macroscopic contaminants have not yet been analyzed systematically. In this study, to close this knowledge gap, virgin polypropylene (PP) was systematically contaminated with paper, aluminum, sand, wood, in-mold labels, jute fibers and long glass-fibers. Additionally, three commercially available post-consumer PP recyclates were investigated. In a two-stage process, all materials were injection-molded into plates and subsequently milled to specimens. The specimens underwent (i) tensile tests at 50 mm/min, (ii) intermediate-rate tensile tests at 2000 mm/min, and (iii) tensile impact tests. Further, optical microscopy was used to measure the dimensions of the defects on the fracture surfaces. First, the influences of various types and quantities of contamination were evaluated. No significant effects were detected, as the matrix material was very brittle. Compared to the virgin reference grade, most samples showed lower strain-at-break values, except for those with labels and long glass-fibers, for which strain values increased. All PP post-consumer recyclates exhibited a more pronounced ductile behavior, although the contaminations incorporated gave rise to relatively high standard deviations. Second, in a comparison of various testing speeds, a greater influence of contaminants was detected in test (iii). Samples taken from a position close to the sprue had better mechanical properties than samples taken from the opposite side of the plate, as contaminants tend to flow to the end of the produced part. Finally, a non-linear relationship between the energy needed for fracture in testing methods (ii) and (iii) and the dimensions of the contamination on the fracture surface was found.
The use of fossil resources and their negative environmental impacts has awakened the awareness of the petrochemical industry. Hereby, we are presenting some upstream industrial scalable and commercial solutions to process sustainable feedstocks, either biogenic or recycled, to produce drop-in hydrocarbons that can be converted into light olefins using the same assets and infrastructure currently established in the petrochemical industry (e.g. steam crackers), reducing the environmental impact of large-volume chemicals such as ethylene, propylene and benzene, which are the most demanded building blocks in the petrochemical value chain. Mass balanced certified co-processing of biogenic and recycled waste plastics as raw materials, are the key for the de-fossilisation of the petrochemical industry. Production of polypropylene (PP) using renewable feedstock can reduce the GHG above 80% or 3.8 kg CO2eq/kg in comparison with the fossil-based. For making a higher impact in the plastic industry, a full integration of the value chain is needed to guarantee allocation of the sustainable credits to targeted products. As a showcase, a collaboration project between partners in different parts of the value chain to produce biobased PP thermoformed plastic cups, is presented. As a result from this collaboration, PP cups with final properties identical in range to the traditional fossil were obtained and the renewable hydrocarbons could be identified in the product using C14. Drop-in solutions using renewable or recycled feedstock is paving the way in the petrochemical industry to obtaining sustainable products with low impact in the current downstream infrastructure.
Ayatullah Elsayed is a Ph.D. candidate in the Mechanical Engineering Department at York University, Canada. Her research area is additive manufacturing of polymeric smart materials for energy harvesting and sensing applications. She is the holder of NSERC scholarship. Aya's research experience in the field of material fabrication and energy harvesting includes the fabrication of nanotubes, nanofibers, nanoparticles, and several characterization techniques, such as SEM, Raman, XRD, and electrochemical measurement techniques. In addition to the conventional mechanical testing, including tension, bending, impact, fatigue and mechanical wear test. Aya obtained her bachelor's degree in Materials Engineering from Ain Shams University (2012). After graduation, she worked as a research assistant at the American University in Cairo (AUC) on a project for biodegradable polymer composites and their dynamic characterization. Aya obtained her Master's degree from the AUC where she worked on the fabrication and characterization of smart nanomaterials for energy harvesting at Energy Materials Laboratory (EML). During this time, Aya also served as Teaching Assistant in the Design and Production Engineering department at Ain Shams University.
Tim Womer is the President of TWWomer & Associates, LLC. He was the 2006-2007 President of the Society of Plastics Engineers and served on the SPE Extrusion Board of Directors for over 22 years including serving as a Chairman in 1999-2000. Tim is a recognized authority in plastics technology and machinery with a career spanning over 40 years; having worked for other companies such as Xaloy, Inc., Spirex Corporation, Conair Group and NRM Corporation. Tim has designed thousands of screws that have been used in all areas of single-screw plasticizing, such as extrusion, blow molding and injection molding. Numerous patents have been issued for his inventions of screws, mixers, processes and other products. In 2012, Tim was inducted into the Plastics Hall of Fame for his contributions to the Plastics Industry, currently the Senior Vice-President of the Plastics Hall of Fame and is also active member of the Plastics Pioneers Association. Tim is only one of six SPE members to ever receive three of SPE's highest awards which include, Distinguished Member, Honored Service and Fellows. Tim remains active in SPE by speaking at various SPE events and serving on the Grants Committee of the SPE Foundation.
ICME has been successfully employed in the design of metals. Inthe Ford Virtual Aluminum Casting project [3], a Computer-aided Engineering(CAE) tool is developed for the P-S-P-P prediction. The thermal history ofcasting process is used to predict the resultant microstructure features(microporosity, eulectic phases, and precipitate phase); the microstructureinformation is used in the prediction of mechanical property (yield strength,fatigue, etc.); the material properties are finally input into the analysisof the cast aluminum cylinder heads ami blocks to predict the residualstresses and durability. In the General Motors Virtual Casting ComponentDevelopment project [6], the aluminum casting process of an engine block isanalyzed and optimized using the ICME methodology. The microstructure anddefects (porosity, crack, etc.) of the casted aluminum component arepredicted based on the casting process simulation to support productperformance analysis, such as durability and reliability. Advancedcomputational methods are also developed for the prediction of the P-S-Prelations of aluminum, such as the solute strengthening and warm formability[7, 8]. Similar developments have also been done on magnesium to provide thecomputational modules for the ICME development, such as the P-P(process-property) modeling of magnesium to understand the solid-solutionstrengthening behavior [9]. However, an automatic process integration andoptimization workflow for P-S-P-P has not been developed in the existing ICMEprojects due to the limitations in high performance computing capability,simulation tools and optimization tools when those projects were done. 2b1af7f3a8
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